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郑彦臻  
研究领域(方向)

1.无机配位材料与功能配合物

2.分子基磁性材料与分子磁学

3.分子量子自旋电子器件

4.团簇与超分子化学

5.金属有机化学

个人及工作简历

郑彦臻现为西安交通大学教授,《中国稀土学报》、《中国化学快报》、及Polyoxometalates青年编委,Magnetochemistry编委;2007年博士毕业于中山大学,曾入选德国洪堡学者(2007)、欧盟玛丽居里学者(2009)、国家特聘青年专家(2012)、仲英青年学者(2017)、科技部中青年科技创新领军人才(2018),2021年入选国家重大人才工程(领军人才);其主要研究方向是分子基磁性材料及功能配合物,迄今主持或参与包括国家自然科学基金在内的研究课题共十余项,在JACSAngew ChemNat CommunAdv MaterMatterChem等学术期刊发表论文180余篇。

教育背景

2002-2007                  博士,无机化学专业(中山大学)

1998-2002                  学士,应用化学专业(中山大学)

工作经历

2011年-今       前沿科学技术研究院教授(西安交通大学)

2019年7月       法国波尔多大学及帕斯卡研究中心访问教授

2018年-今       前沿科学技术研究院荣誉副院长(西安交通大学)

2014年-2018年   前沿科学技术研究院副院长(西安交通大学)

2009年-2011年   欧盟玛丽居里学者(英国曼彻斯特大学)

2009年-2009年   博士后研究助理(德国亚琛工业大学)

2007年-2009年   洪堡学者(德国卡尔斯鲁厄大学)

科研项目

1.  国家自然科学基金委面上项目,低价态稀土单分子磁体的构筑与性质研究,22375157,2024-2027。

2.  国家自然科学基金委面上项目,含氟稀土团簇的设计合成及其磁、光性质研究,21971203,2020-2023。

3. 金属材料强度国家重点实验室开放课题,20182016,分子基磁性材料的可控合成与理论研究,2018-2020。 

4.  国家自然科学基金委面上项目,21773130,赝两配位单分子磁体的磁构关系、可控合成及高性能化研究,2018-2021。    

5.  国家自然科学基金委重点国际(地区)合作研究项目,21620102002, 低维磁分子固体的结构设计与功能调控,2017-2021。  

学术及科研成果、专利、论文
1.Bis-Alkoxide Dysprosium(III) Crown Ether Complexes Exhibit Tunable Air Stability and Record Energy Barrier; Wen-Jie Xu, Qian-Cheng Luo, Zi-Han Li, Yuan-Qi Zhai, and Yan-Zhen Zheng* Adv. Sci. 2024, article accepted. DOI: 10.1002/advs.202308548. (IF=15.1).

2.Gd-based Molecular Coolants: Aggregating for Better Magnetocaloric Effect; Yuan-Qi Zhai, Wei-Peng Chen,* Marco Evangelisti, Zhendong Fu and Yan-Zhen Zheng* Aggregate 2024, article accepted. (IF=18.8).

3. Thermally Stable Terbium(II) and Dysprosium(II) Bis-amidinate Complexes; Peng-Bo Jin, Qian-Cheng Luo, Gemma K. Gransbury, Iñigo J. Vitorica-Yrezabal, Tomáš Hajdu, Ilya Strashnov, Eric J. L. McInnes, Richard E. P. Winpenny, Nicholas F. Chilton*, David P. Mills*, and Yan-Zhen Zheng* J. Am. Chem. Soc. 2023, 145, 27993–28009. (IF = 15).

4.Mitigating Raman relaxation for high-temperature single-molecule magnets; Qian-Cheng Luo and Yan-Zhen Zheng* Trends Chem. 2023, 5, 869-872. (IF=15.7).

5.Suppression of zero-field quantum tunneling of magnetization by a fluorido bridge for a "very hard" 3d-4f single-molecule magnet; Bo-Kai Ling, Yuan-Qi Zhai, Peng-Bo Jin, Hong-Fan Ding, Xu-Feng Zhang, Yi Lv, Zhendong Fu, Jiewei Deng, Michael Schulze, Wolfgang Wernsdorfer, Yan-Zhen Zheng* Matter, 2022, 3485-3498. (IF=18.9).

6.{ScnGdn} Heterometallic Rings: Tunable Ring Topology for Spin Wave Excitations; Hao-Lan Zhang, Yuan-Qi Zhai, Hiroyuki Nojiri, Christian Schröder, Hung-Kai Hsu, Yi-Tsu Chan, Zhendong Fu, Yan-Zhen Zheng* J. Am. Chem. Soc. 2022, 144, 15193–15202. (IF = 15).

7.Ligand Fluorination to Mitigate the Raman Relaxation of Dy(III) Single-Molecule Magnets: A Combined Terahertz, Far-IR and Vibronic Barrier Model Study; Yan Ma,Yuan-Qi Zhai,Qian-Cheng Luo,You-Song Ding,Yan-Zhen Zheng* Angew. Chem. Int. Ed. 2022, e202206022. (IF = 16.6).

8.Tetraanionic arachno-Carboranyl Ligand Imparts Strong Axiality to Terbium(III) Single-Molecule Magnets; Peng-Bo Jin, Ke-Xin Yu, Qian-Cheng Luo, Ye-Ye Liu, Yuan-Qi Zhai and Yan-Zhen Zheng* Angew. Chem. Int. Ed. 2022, e202203285. (IF = 16.6).

9.Reentrant Spin Glass and Large Coercive Field Observed in a Spin Integer Dimerized Honeycomb Lattice; Yuan‐Qi Zhai,Yi‐Fei Deng ,Zhendong Fu*,Erxi Feng ,Yixi Su ,Takuya Shiga ,Hiroki Oshio and Yan‐Zhen Zheng* Adv. Funct. Mater. 2021, 31, 2004744, (IF = 19, featured on back cover).

10.Enhancing Magnetic Hysteresis in Single-Molecule Magnets by Ligand Functionalization; Ke-Xin Yu, Jon G.C. Kragskow,You-Song Ding, Yuan-Qi Zhai, Daniel Reta, Nicholas F. Chilton*, Yan-Zhen Zheng* Chem, 2020, 6, 1777-1793, (IF = 23.5).

11.Single-Molecule Toroic Design through Magnetic Exchange Coupling; Hao-Lan Zhang, Yuan-Qi Zhai, Lei Qin, Liviu Ungur, Hiroyuki Nojiri, Yan-Zhen Zheng* Matter, 2020, 2, 1481-1493, (IF=18.9, featured on cover).

12.The Gigantic {Ni36Gd102} Hexagon: A Sulfate-Templated “Star-of-David” for Photocatalytic CO2 Reduction and Magnetic Cooling; Wei-Peng Chen, Pei-Qin Liao, Peng-Bo Jin, Lei Zhang, Bo-Kai Ling, Shi-Cheng Wang, Yi-Tsu Chan, Xiao-Ming Chen, and Yan-Zhen Zheng* J. Am. Chem. Soc. 2020, 142, 4663–4670 (IF = 15, featured on cover).

13. Dysprosiacarboranes: A New Type of Organometallic Single‐Molecule Magnet; Peng-Bo Jin, Yuan-Qi Zhai, Ke-Xin Yu, Richard E. P. Winpenny, and Yan-Zhen Zheng* Angew. Chem. Int. Ed. 2020, 59, 9350-9354 (IF = 16.6).

14. Field- and temperature-dependent quantum tunnelling of the magnetisation in a large barrier single-molecule magnet; Y. -S. Ding , K.-X. Yu , D.Reta, F.Ortu, R. E.P. Winpenny , Y.-Z. Zheng*, Nicholas F. Chilton*, Nat. Commun., 2018, 9, 3134 (IF = 16.6).

15. Quantum Monte Carlo simulations of a giant {Ni21Gd20} cage with a S =91 spin ground state; W.-P. Chen, J. Singleton, L. Qin, A. Camón, L. Engelhardt,* F. Luis, R. E. P. Winpenny,* and Y.-Z. Zheng*, Nat. Commun., 2018, 9, 2107 (IF = 16.6).

16. Quantum Monte Carlo Simulations and High-Field Magnetization Studies of Antiferromagnetic Inter-actions in a Giant Hetero-Spin Ring; L. Qin, J. Singleton, W.-P. Chen, H. No-jiri, L. Engelhardt,* R. E. P. Winpenny,* and Y.-Z. Zheng*, Angew. Chem. Int. Ed., 2017, 56, 16571-16574. (IF = 16.6).

17. Topological Self-Assembly of Highly-Symmetric Lanthanide Clusters: A Magnetic Study of Exchan-ge-Coupling “Fingerprints” in Giant Gadolinium(III) Cages; L. Qin, G.-J. Zhou, Y.-Z. Yu, H. Nojiri, C. Schröder*, R. E. P. Winpenny* and Y.-Z. Zheng*, J. Am. Chem. Soc., 2017, 139, 16405–16411. (IF = 15).

18. On Approaching the Limit of Molecular Magnetic Anisotropy:A Near-Perfect Pentagonal Bipyram-idal Dysprosium(III) Single-Molecule Magnet; Y.-S. Ding, N. F. Chilton,* R. E. P. Winpenny,* and Y.-Z. Zheng*, Angew. Chem. Int. Ed., 2016, 55, 16071–16074. (IF = 16.6, ESI hot paper).

19. A “Molecular Water Pipe”: A Giant Tubular Cluster {Dy72} Exhibits Fast Proton Tra-nsport and Slo-w Magnetic Relaxation; L. Qin, Y.-Z. Yu, P.-Q. Liao, W. Xue, Z. Zheng, X.-M. Chen and Y.-Z. Zheng*, Adv. Mater., 2016, 28, 10772–10779. (IF = 29.4).

20. A Mixed-Ligand Approach for a Gigantic and Hollow Heterometallic Cage {Ni64RE96} for Gas Sep-aration and Magnetic Cooling Applications; W.-P. Chen, P.-Q. Liao, Y. Yu, Z. Zheng, X.-M. Chen and Y.-Z. Zheng*, Angew. Chem. Int. Ed., 2016, 55, 9375-9379. (IF = 16.6).

21. Molecule-based magnetic coolers; Y.-Z. Zheng*, G.-J. Zhou, Z. Zheng, R. E. P. Winpenny, Chem. Soc. Rev., 2014, 43, 1462-1475. (入选ESI高被引, IF = 46.2).

22. A symbol approach for classification of molecule-based magnetic materials exemplifi-ed by coordi-nation polymers of metal carboxylates; Y.-Z. Zheng*, Z. Zheng, X.-M. Chen, Coord. Chem. Rev., 2014, 258-259, 1-15. (入选ESI高被引, IF = 20.6).

23. Co-Ln Mixed-Metal Phosphonate Grids and Cages as Molecular Magnetic Refrigerants; Y.-Z. Zheng, M. Evangelisti, F. Tuna, R. E. P. Winpenny,* J. Am. Chem. Soc., 2012, 134, 1057-1065. (入选ESI高被引, IF = 15). 

书籍章节


1. Han Tian, You-Song Ding, and Yan-Zhen Zheng. "Lanthanide Clusters Toward Single-Molecule Magnets." 2016, pp209-314.

2. You-Song Ding, Richard E. P. Winpenny and Yan-Zhen Zheng. “Comprehensive Coordination Chemistry III——3d- and 4f-Based Single Molecule Magnets”. 2021, pp595-619.

3. Hao-Lan Zhang, Yuan-Qi Zhai, and Yan-Zhen Zheng. "Rationalization of Room-Temperature Single-Molecule Toroics via Exchange Coupling", 2022, pp107-131.

4. 郑彦臻, 童明良. “磁性配位聚合物”, 配位聚合物化学(下册) 卜显和主编, 科学出版社, 2019, pp153-192. ISBN:978-7-03-060762-1.

专利公开

1. 郑彦臻,王艳艳,秦雷, 周国军,“一种含稀土氢氧化物的磁制冷材料及制备方法”,发明专利,专利号:ZL 2014 1 0817811.0

2. 郑彦臻,凌博恺,“一种氟桥连稀土分子磁制冷材料及制备方法”,发明专利,专利号:ZL 2019 1 1368861.4

3. 郑彦臻,凌博恺,“一种氟桥连稀土分子簇荧光材料及制备方法”,发明专利,专利号:ZL 2019 1 1370953.6

获奖情况

2019 陕西省高等学校科学技术奖励二等奖

2018 中华医学会一等奖(第六)

2017 亚洲国际学术论坛杰出授课奖

2013 广东省科学技术(自然类)一等奖(第三)

2009 欧盟居里夫人奖学金(Marie Curie Fellowship)

2007 德国洪堡奖学金(Humboldt Fellowship)

联系方式
电子邮箱:zheng.yanzhen@xjtu.edu.cn
联系电话:
联系地址:陕西省西安市雁翔路99号交大科技园西二楼A202-1,邮编710054
更新日期:2024-03-26